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Watch Chuck Season 3 Episode 3. Chuck vs. the Angel de la Muerte. Chuck (Zachary Levi) must use his relationship with Awesome (Ryan McPartlin) to protect a visiting dictator, Premier Goya (guest star Armand Assante), who is the target of an assassination. While Awesome is excited about the prospect of being a spy, Chuck (Zachary Levi) is more concerned about Awesome and Ellie’s (Sarah Lancaster) safety.